Yes, even with a small amount of urine in the bladder, sex in some positions can be uncomfortable.
You may want to experiment with various positions (positions.com) and try one that doesn't put so much weight and pressure on your bladder. In particular, the missionary position can be awkward for this reason... however, rear entry (doggie) or woman astride (cowgirl) can be much better... but there are many other options as well.
Check them out and discuss this with your bf. If he's at all sensitive to your needs, he'll be willing to accomodate your concerns and options.
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